'Chemical engineering is the field of applied science that employs physical, chemical, and biological rate processes for the betterment of humanity'. This opening sentence of Chapter 1 has been the underlying paradigm of chemical engineering. Chemical Engineering: An Introduction is designed to enable the student to explore the activities in which a modern chemical engineer is involved by focusing on mass and energy balances in liquid-phase processes. Problems explored include the design of a feedback level controller, membrane separation, hemodialysis, optimal design of a process with chemical reaction and separation, washout in a bioreactor, kinetic and mass transfer limits in a two-phase reactor, and the use of the membrane reactor to overcome equilibrium limits on conversion. Mathematics is employed as a language at the most elementary level. Professor Morton M. Denn incorporates design meaningfully; the design and analysis problems are realistic in format and scope.
Presenting a systematic model reduction and hierarchical controller design framework for broad classes of integrated process systems encountered in practice, this book first studies process systems with large material recycle and/or with small purge streams, followed by systems with energy integration. Step-by-step model reduction procedures are developed to derive nonlinear reduced models of the dynamics in each time scale. Hierarchical control architectures consisting of coordinated levels of control action in different time scales are proposed for each class of process systems considered to enforce stability, tracking performance and disturbance rejection. Numerous process applications are discussed in detail to illustrate the application of the methods and their potential to improve process operations. MATLAB codes are also presented to guide further application of the methods developed and facilitate practical implementations.
An introductory 2002 textbook, Process Control covers the most essential aspects of process control suitable for a two-semester course. While classical techniques are discussed, also included is a discussion of state space modeling and control, a modern control topic lacking in most introductory texts. MATLAB, a popular engineering software package, is employed as a powerful yet approachable computational tool. Text examples demonstrate how root locus, Bode plots, and time domain simulations can be integrated to tackle a control problem. Classical control and state space designs are compared. Despite the reliance on MATLAB, theory and analysis of process control are well-presented, creating a well-rounded pedagogical text. Each chapter concludes with problem sets, to which hints or solutions are provided. A web site provides excellent support in the way of MATLAB outputs of text examples and MATLAB sessions, references, and supplementary notes. Students and professionals will find it
'Chemical engineering is the field of applied science that employs physical, chemical, and biological rate processes for the betterment of humanity'. This opening sentence of Chapter 1 has been the underlying paradigm of chemical engineering. Chemical Engineering: An Introduction is designed to enable the student to explore the activities in which a modern chemical engineer is involved by focusing on mass and energy balances in liquid-phase processes. Problems explored include the design of a feedback level controller, membrane separation, hemodialysis, optimal design of a process with chemical reaction and separation, washout in a bioreactor, kinetic and mass transfer limits in a two-phase reactor, and the use of the membrane reactor to overcome equilibrium limits on conversion. Mathematics is employed as a language at the most elementary level. Professor Morton M. Denn incorporates design meaningfully; the design and analysis problems are realistic in format and scope.
This book is about radioactive gases and particles which are dispersed in the environment, either from natural causes, or following nuclear test and accidental emissions. In the first five chapters of this book, the formation and properties of radioactive aerosols are described. Radon, which is of natural origin, is treated at some length, because its contribution to background radiation dose is important. Chapters describe the release of fission products, tritium and plutonium, in bomb tests and nuclear accidents. Particular reference is made to the pathways leading via agricultural products to man. The emphasis then changes to cover experimental aspects of radioactive aerosols. For example, problems in micrometeorology, the study of mass transfer, the mechanics of the human lung and uptake of lead from motor exhausts. Arthur Chamberlain has worked at the Atomic Energy Research Establishment at Harwell for thirty years as the leader of the Aerosol Group. It is a unique exposition and
The term 'transport phenomena' describes the fundamental processes of momentum, energy, and mass transfer. This text provides a thorough discussion of transport phenomena, laying the foundation for understanding a wide variety of operations used by chemical engineers. The book is arranged in three parallel parts covering the major topics of momentum, energy, and mass transfer. Each part begins with the theory, followed by illustrations of the way the theory can be used to obtain fairly complete solutions, and concludes with the four most common types of averaging used to obtain approximate solutions. A broad range of technologically important examples, as well as numerous exercises, are provided throughout the text. Based on the author's extensive teaching experience, a suggested lecture outline is also included. This book is intended for first-year graduate engineering students; it will be an equally useful reference for researchers in this field.
Heterogeneous catalysis is widely used in chemical, refinery, and pollution-control processes. For this reason, achieving optimal performance of catalysts is a significant issue for chemical engineers and chemists. This book addresses the question of how catalytic material should be distributed inside a porous support in order to obtain optimal performance. It treats single and multiple reaction systems, isothermal and nonisothermal conditions, pellets, monoliths, fixed-bed reactors, and membrane reactors. The effects of physicochemical and operating parameters are analyzed to gain insight into the underlying phenomena governing the performance of optimally designed catalysts. Throughout, the authors offer a balanced treatment of theory and experiment. Particular attention is given to problems of commercial importance. With its thorough treatment of the design, preparation, and utilization of supported catalysts, this book will be an ideal resource for graduate students, researchers
Chemical separations are of central importance in many areas of environmental science, whether it is the clean up of polluted water or soil, the treatment of discharge streams from chemical processes, or modification of a specific process to decrease its environmental impact. This book is an introduction to chemical separations, focusing on their use in environmental applications. The authors first discuss the general aspects of separation technology as a unit operation. They also describe how property differences are used to generate separations, the use of separating agents, and the selection criteria for particular separation techniques. The general approach for each technology is to present the chemical and/or physical basis for the process and explain how to evaluate it for design and analysis. The book contains many worked examples and homework problems. It is an ideal textbook for undergraduate and graduate students taking courses on environmental separations or environmental
The behavior of a chemical system is affected by many physicochemical parameters. The sensitivity of the system's behavior to changes in parameters is known as parametric sensitivity. When a system operates in a parametrically sensitive region, its performance becomes unreliable and changes sharply with small variations in parameters. Thus, it would be of great value to predict sensitivity behavior in chemical systems. This book is the first to provide a thorough treatment of the concept of parametric sensitivity and the mathematical tool it generated, sensitivity analysis. The emphasis is on applications to real situations. The book begins with definitions of various sensitivity indices and describes the numerical techniques used for their evaluation. Extensively illustrated chapters discuss sensitivity analysis in a variety of chemical reactors - batch, tubular, continuous-flow, fixed-bed - and in combustion systems, air pollution, and metabolic processes. Chemical engineers
Heterogeneous catalysis is widely used in chemical, refinery, and pollution-control processes. For this reason, achieving optimal performance of catalysts is a significant issue for chemical engineers and chemists. This book addresses the question of how catalytic material should be distributed inside a porous support in order to obtain optimal performance. It treats single and multiple reaction systems, isothermal and nonisothermal conditions, pellets, monoliths, fixed-bed reactors, and membrane reactors. The effects of physicochemical and operating parameters are analyzed to gain insight into the underlying phenomena governing the performance of optimally designed catalysts. Throughout, the authors offer a balanced treatment of theory and experiment. Particular attention is given to problems of commercial importance. With its thorough treatment of the design, preparation, and utilization of supported catalysts, this book will be an ideal resource for graduate students, researchers
Gas-solid flows are involved in numerous industrial processes and occur in various natural phenomena. This authoritative book addresses the fundamental principles that govern gas-solid flows and the application of these principles to various gas-solid flow systems. The book is arranged in two parts: Part I deals with basic relationships and phenomena, including particle size and properties, collision mechanics, momentum transfer, heat and mass transfer, basic equations, and intrinsic phenomena in gas-solid flows. Part II discusses gas-solid flow systems of industrial interest such as gas-solid separators, hoppers and standpipes, dense-phase fluidised beds, fluidised beds, pneumatic conveying systems, and heat and mass transfer in fluidisation systems. As a comprehensive text on gas-solid flows, including end-of-chapter problems, this book is aimed at graduate students, but will also be useful to a broad range of engineers and applied scientists.
This book presents the current state of the art in computational models for turbulent reacting flows, and analyzes carefully the strengths and weaknesses of the various techniques described. The focus is on formulation of practical models as opposed to numerical issues arising from their solution. A theoretical framework based on the one-point, one-time joint probability density function (PDF) is developed. It is shown that all commonly employed models for turbulent reacting flows can be formulated in terms of the joint PDF of the chemical species and enthalpy. Models based on direct closures for the chemical source term as well as transported PDF methods are covered in detail. An introduction to the theory of turbulent and turbulent scalar transport is provided for completeness. The book is aimed at chemical, mechanical, and aerospace engineers in academia and industry, as well as developers of computational fluid dynamics codes for reacting flows.
Process Control, first published in 2002, covers the most essential aspects of process control for a two-semester introductory course. Theory and analysis of process control are well-presented, and MA
Master the principles of thermodynamics with this comprehensive undergraduate textbook, carefully developed to provide students of chemical engineering and chemistry with a deep and intuitive understanding of the practical applications of these fundamental ideas and principles. Logical and lucid explanations introduce core thermodynamic concepts in the context of their measurement and experimental origin, giving students a thorough understanding of how theoretical concepts apply to practical situations. A broad range of real-world applications relate key topics to contemporary issues, such as energy efficiency, environmental engineering and climate change, and further reinforce students' understanding of the core material. This is a carefully organized, highly pedagogical treatment, including over 500 open-ended study questions for discussion, over 150 varied homework problems, clear and objective standards for measuring student progress, and a password-protected solution manual for
Addressing all aspects of the design, modeling and simulation of chromatographic processes, this result-oriented primer provides a practical guide to all the necessary approaches, methodologies and tools. Beginning with key definitions and concepts, it builds up from the most simple to the most complex situations, including multicomponent systems, non-uniform velocity profiles, bed instability, particle size distributions, and the influence of complex environments on chromatographic process design. In addition to covering classical approaches, it introduces efficient tools for investigating chromatographic processes, such as the 'Russian-Lego' approach for linear systems, phenomenological models, and specific shortcuts for deriving the key properties of industrial processes. With an emphasis on real-world problems and applications, step-by step modeling design guidelines, and detailed exercises for self-assessment, this is a must-have guide for practitioners and researchers working in
Learn classical thermodynamics alongside statistical mechanics with this fresh approach to the subjects. Molecular and macroscopic principles are explained in an integrated, side-by-side manner to give students a deep, intuitive understanding of thermodynamics and equip them to tackle future research topics that focus on the nanoscale. Entropy is introduced from the get-go, providing a clear explanation of how the classical laws connect to the molecular principles, and closing the gap between the atomic world and thermodynamics. Notation is streamlined throughout, with a focus on general concepts and simple models, for building basic physical intuition and gaining confidence in problem analysis and model development. Well over 400 guided end-of-chapter problems are included, addressing conceptual, fundamental, and applied skill sets. Numerous worked examples are also provided together with handy shaded boxes to emphasize key concepts, making this the complete teaching package for
Learn classical thermodynamics alongside statistical mechanics with this fresh approach to the subjects. Molecular and macroscopic principles are explained in an integrated, side-by-side manner to give students a deep, intuitive understanding of thermodynamics and equip them to tackle future research topics that focus on the nanoscale. Entropy is introduced from the get-go, providing a clear explanation of how the classical laws connect to the molecular principles, and closing the gap between the atomic world and thermodynamics. Notation is streamlined throughout, with a focus on general concepts and simple models, for building basic physical intuition and gaining confidence in problem analysis and model development. Well over 400 guided end-of-chapter problems are included, addressing conceptual, fundamental, and applied skill sets. Numerous worked examples are also provided together with handy shaded boxes to emphasize key concepts, making this the complete teaching package for
The chemical industry is changing, going beyond commodity chemicals to a palette of higher value added products. This groundbreaking book, now revised and expanded, documents this change and shows how to meet the challenges implied. Presenting a four-step design process - needs, ideas, selection, manufacture - the authors supply readers with a simple design template that can be applied to a wide variety of products. Four new chapters on commodities, devices, molecules/drugs and microstructures show how this template can be applied to products including oxygen for emphysema patients, pharmaceuticals like taxol, dietary supplements like lutein, and beverages which are more satisfying. For different groups of products the authors supply both strategies for design and summaries of relevant science. Economic analysis is expanded, emphasizing the importance of speed-to-market, selling ideas to investors and an expectation of limited time in the market. Extra examples, homework problems and
Designed for introductory undergraduate courses in fluid mechanics for chemical engineers, this stand-alone textbook illustrates the fundamental concepts and analytical strategies in a rigorous and systematic, yet mathematically accessible manner. Using both traditional and novel applications, it examines key topics such as viscous stresses, surface tension, and the microscopic analysis of incompressible flows which enables students to understand what is important physically in a novel situation and how to use such insights in modeling. The many modern worked examples and end-of-chapter problems provide calculation practice, build confidence in analyzing physical systems, and help develop engineering judgment. The book also features a self-contained summary of the mathematics needed to understand vectors and tensors, and explains solution methods for partial differential equations. Including a full solutions manual for instructors available at www.cambridge.org/deen, this balanced
Most of the shaping in the manufacture of polymeric objects is carried out in the melt state, as it is a substantial part of the physical property development. Melt processing involves an interplay between fluid mechanics and heat transfer in rheologically complex liquids, and taken as a whole it is a nice example of the importance of coupled transport processes. This book is on the underlying foundations of polymer melt processing, which can be derived from relatively straightforward ideas in fluid mechanics and heat transfer; the level is that of an advanced undergraduate or beginning graduate course, and the material can serve as the text for a course in polymer processing or for a second course in transport processes.