Artificial Receptors For Chemical Sensors
商品資訊
ISBN13:9783527323579
出版社:John Wiley & Sons Inc
作者:Mirsky
出版日:2010/12/15
裝訂/頁數:精裝/486頁
商品簡介
作者簡介
Anatoly K. Yatsimirsky is Professor of Chemistry at the National Autonomous University of Mexico in Mexico City. He obtained his PhD and Dr. Sc. Degrees from Moscow Lomonosov State University, where he was Professor prior to his move to Mexico in 1992. He spent Visiting Scholar/Professor stays at Milan University, Italy, in 1980/81 and at the University of California at Santa Barbara in 1998/99. His research is focused on physical organic chemistry and metal complex catalysis and he is the author of 160 peer-reviewed scientific publications including a monograph “Principles and Methods in Supramolecular Chemistry “ by John Wiley & Sons and further book contributions.
目次
List of Contributors.
1 Quantitative Characterization of Affinity Properties of Immobilized Receptors (Vladimir M. Mirsky).
1.1 Introduction.
1.2 Measurements Under Equilibrium Conditions.
1.3 Kinetic Measurements.
1.4 Analysis of Temperature Dependencies.
1.5 Experimental Techniques.
References.
2 Selectivity of Chemical Receptors (Hans-Jörg Schneider and Anatoly K. Yatsimirsky).
2.1 Introduction.
2.2 Some General Considerations on Selectivity.
2.3 Correlation Between Selectivity and Affinity.
2.4 Crown Ether and Cryptand Complexes: Hole Size Fitting and Other Effects.
2.5 Recognition of Transition and Heavy Metal Ions.
2.6 Recognition via Ion Pairing.
2.7 Hydrogen Bonded Complexes and Solvent Effects.
2.8 Lewis Acid Receptors.
2.9 Complexes with Stacking and van der Waals Interactions.
2.10 Multifunctional Receptors for Recognition of Complex Target Molecules.
2.11 Conclusions.
References.
3 Combinatorial Development of Sensing Materials (Radislav A. Potyrailo).
3.1 Introduction.
3.2 General Principles of Combinatorial Materials Screening.
3.3 Opportunities for Sensing Materials.
3.4 Designs of Combinatorial Libraries of Sensing Materials.
3.5 Discovery and Optimization of Sensing Materials Using Discrete Arrays.
3.6 Optimization of Sensing Materials Using Gradient Arrays.
3.7 Emerging Wireless Technologies for Combinatorial Screening of Sensing Materials.
3.8 Summary and Outlook.
References.
4 Fluorescent Cyclodextrins as Chemosensors for Molecule Detection in Water (Hiroshi Ikeda).
4.1 Introduction.
4.2 Pyrene-Appended Cyclodextrins.
4.3 Fluorophore–Amino Acid–CD Triad Systems.
4.4 Molecular Recognition by Regioisomers of Dansyl-Appended CDs.
4.5 Turn-On Fluorescent Chemosensors.
4.6 Effect of Protein Environment on Molecule Sensing.
4.7 CD–Peptide Conjugates as Chemosensors.
4.8 Immobilized Fluorescent CD on a Cellulose Membrane.
4.9 Conclusion.
References.
5 Cyclopeptide Derived Synthetic Receptors (Stefan Kubik).
5.1 Introduction.
5.2 Receptors for Cations.
5.3 Receptors for Ion Pairs.
5.4 Receptors for Anions.
5.5 Receptors for Neutral Substrates.
5.6 Conclusion.
References.
6 Boronic Acid-Based Receptors and Chemosensors (Xiaochuan Yang, Yunfeng Cheng, Shan Jin, and Binghe Wang).
6.1 Introduction.
6.2 De Novo Design.
6.3 Combinatorial Approaches.
6.4 Template Directed Synthesis.
References.
7 Artificial Receptor Compounds for Chiral Recognition (Thomas J. Wenzel and Ngoc H. Pham).
7.1 Introduction.
7.2 Cyclodextrins.
7.3 Crown Ethers.
7.4 Calixarenes.
7.5 Calix[4]resorcinarenes.
7.6 Miscellaneous Receptor Compounds.
7.7 Metal-Containing Receptor Compounds.
References.
8 Fullerene Receptors Based on Calixarene Derivatives (Pavel Lhoták and Ondrej Kundrát).
8.1 Introduction.
8.2 Calixarenes.
8.3 Solid State Complexation by Calixarenes.
8.4 Complexation in Solution.
8.5 Calixarenes as Molecular Scaffolds.
8.6 Outlook.
References.
9 Guanidinium Based Anion Receptors (Carsten Schmuck and Hannes Yacu Kuchelmeister).
9.1 Introduction.
9.2 Instructive Historical Examples.
9.3 Recent Advances in Inorganic Anion Recognition.
9.4 Organic and Biological Phosphates.
9.5 Polycarboxylate Binding.
9.6 Amino Acid Recognition.
9.7 Dipeptides as Substrate.
9.8 Polypeptide Recognition.
9.9 Conclusion.
References.
10 Artificial Receptors Based on Spreader-Bar Systems (Thomas Hirsch).
References.
11 Potential of Aptamers as Artificial Receptors in Chemical Sensors (Bettina Appel, Sabine Müller, and Sabine Stingel).
11.1 Introduction.
11.2 Generation and Synthesis of Aptamers.
11.3 Aptamer Arrays.
11.4 Techniques for Readout of Ligand Binding to the Aptamer.
11.5 Outlook/Summary.
References.
12 Conducting Polymers as Artificial Receptors in Chemical Sensors (Ulrich Lange, Nataliya V. Roznyatovskaya, Qingli Hao, and Vladimir M. Mirsky).
12.1 Introduction.
12.2 Transducers for Artificial Receptors Based on Conducting Polymers.
12.3 Intrinsic Sensitivity of Conducting Polymers.
12.4 Conducting Polymers Modified with Receptor Groups.
12.5 Conclusion.
References.
13 Molecularly Imprinted Polymers as Artificial Receptors (Florian Meier and Boris Mizaikoff).
13.1 Introduction.
13.2 Fundamentals of Molecular Imprinting.
13.3 Polymer Formats and Polymerization Methods for MIPs.
13.4 Evaluation of MIP Performance – Imprinting Efficiency.
13.5 MIPs Mimicking Natural Receptors.
13.6 Conclusions and Outlook.
References.
14 Quantitative Affinity Data on Selected Artificial Receptors (Anatoly K. Yatsimirsky and Vladimir M. Mirsky).
14.1 Structures of Receptors.
References.
Index.
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