Strained Hydrocarbons
商品資訊
ISBN13：9783527317677
出版社：John Wiley & Sons Inc
作者：Dodziuk
出版日：2009/03/18
裝訂／頁數：精裝／492頁
規格：24.8cm*17.8cm*3.2cm (高/寬/厚)
商品簡介
作者簡介
目次
Preface.
List of Contributors.
1 Introduction.
1.1 Initial Remarks (Helena Dodziuk).
1.2 Hydrocarbons with Unusual Spatial Structure: the Need to Finance Basic Research (Helena Dodziuk).
1.3 Computations on Strained Hydrocarbons (Andrey A. Fokin and Peter R. Schreiner).
1.4 Gallery of Molecules That Could Have Been Included in This Book (Helena Dodziuk).
References.
2 Distorted Saturated Hydrocarbons.
2.1 Molecules with Inverted Carbon Atoms (Kata Mlinarić-Majerski).
2.2 Molecules with Planar and Pyramidal Carbon Atoms (Helena Dodziuk).
2.3 A Theoretical Approach to the Study and Design of Prismane Systems (Tatyana N. Gribanova, Vladimir I. Minkin and Ruslan M. Minyaev).
2.4 (CH)2n Cage Structures, ‘in’-‘out’ Isomerism in Perhydrogenated Fullerenes and Planar Cyclohexane Rings (Helena Dodziuk).
2.5 Ultralong C–C Bonds (Takanori Suzuki, Takashi Takeda, Hidetoshi Kawai and Kenshu Fujiwara).
2.6 Ultrashort C–C Bonds (Vladimir Y. Lee and Akira Sekiguchi).
References.
3 Distorted Alkenes.
3.1 Nonplanar Alkenes (Dieter Lenoir, Paul J. Smith and Joel F. Liebman).
3.2 Small Ring and Cage Structures Involving Nonplanar C=C Bonds (Athanassios Nicolaides).
3.3 Strained Cyclic Allenes and Cumulenes (Richard P. Johnson and Kaleen M. Konrad).
References.
4 Strained Aromatic Molecules.
4.1 Nonstandard Benzenes (Paul J. Smith and Joel F. Liebman).
4.2 Distorted Cyclophanes (Henning Hopf).
4.3 Helicenes (Ivo Starý and Irena G. Stará).
4.4 Cycloproparenes (Brian Halton).
References.
5 Fullerenes.
5.1 Introduction (Helena Dodziuk).
5.2 Chemistry Influenced by the Nontypical Structure: Modification of [60]Fullerene (Takuma Hara, Takashi Konno, Yosuke Nakamura and Jun Nishimura).
5.3 Physicochemical Properties and the Unusual Structure of Fullerenes.
5.4 Fullerene Aggregates.
5.5. Endohedral Fullerenes with Neutral Atoms and Molecules (Sho-ichi Iwamatsu).
5.6 Hydrogenated Fullerenes (Mark S. Meier).
5.7 Applications of Fullerenes (Rossimiriam Pereira de Freitas and Jean-François Nierengarten).
References.
6 Carbon Nanotubes.
6.1 The Structure and Properties of Carbon Nanotubes (Anke Krueger).
6.2 The Functionalization of Carbon Nanotubes( Anke Krueger).
6.3 Applications of Carbon Nanotubes (Marc Monthioux).
References.
7 Angle-strained Cycloalkynes (Henning Hopf and Jörg Grunenberg).
7.1 Introduction.
7.2 Cyclopropyne and Cyclobutyne: Speculations and Calculations on Non-isolable Cycloalkynes.
7.3 Cyclopentyne, Cyclohexyne, Cycloheptyne: from Reactive Intermediates to Isolable Compounds.
7.4 The Isolable Angle-strained Cycloalkynes: Cyclooctyne, Cyclononyne, and Beyond.
7.5 Cyclic Polyacetylenes.
7.6 Spectroscopic Properties of Angle-strained Cycloalkynes.
References.
8 Molecules with Labile Bonds: Selected Annulenes and Bridged Homotropilidenes (Richard V. Williams).
8.1 Introduction.
8.2 Annulenes.
8.3 Cyclooctatetraene.
8.4 Bond Shifting, Ring Inversion and Antiaromaticity.
8.5 Valence Isomerization.
8.6 Ions Derived from COT.
8.7 The Higher Annulenes.
8.8 Bridged Homotropilidenes.
8.9 Recent Developments.
8.9 Conclusions.
References.
9 Molecules with Nonstandard Topological Properties: Centrohexaindane, Kuratowski’s Cyclophane and Other Graph-theoretically Nonplanar Molecules (Dietmar Kuck).
9.1 Introduction.
9.2 Topologically Nonplanar Graphs and Molecular Motifs.
9.3 Centrohexaindane.
9.4 K5 versus K3,3 Molecules.
9.5 Kuratowski’s Cyclophane.
9.6 Conclusions.
References.
10 Short-lived Species Stabilized in ‘Molecular’ or ‘Supramolecular Flasks (Helena Dodziuk).
References.
11 Concluding Remarks (Helena Dodziuk).
References.
Index.
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