Kinetics of Cell Carbohydrates
商品資訊
ISBN13：9786203465396
出版社：LAP LAMBERT ACADEMIC PUB
作者：Sonal Choubey
出版日：2021/03/03
裝訂：平裝
規格：22.9cm*15.2cm*0.6cm (高/寬/厚)
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：NT$ 3900 元無庫存，下單後進貨(到貨天數約30-45天)
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The kinetics of uncatalysed and catalysed oxidation of D-ribose by Cerium(IV) has been studied in acidic medium in the temperature range 303-338 K. The reaction has been found to be first order with respect to [D-ribose] in both uncatalysed and catalysed reactions. The rates follow first order kinetics in [Ir(III)] catalysed oxidation reaction. The effect of [HSO4- ] has also been observed. The increase in ionic strength of the medium decreases the rate of uncatalysed reaction while increases catalysed reaction. A 1:2 stoichiometry is observed in the oxidation. From the effect of temperature on the reaction rate, the Arrhenius and activation parameters have been calculated. A suitable mechanism has been proposed and a rate law explaining the experimental results is derived.
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